Solution on the Bethe lattice of a hard core athermal gas with two kinds of particles.

نویسندگان

  • Tiago J Oliveira
  • Jürgen F Stilck
چکیده

Athermal lattice gases of particles with first neighbor exclusion have been studied for a long time as simple models exhibiting a fluid-solid transition. At low concentration the particles occupy randomly both sublattices, but as the concentration is increased one of the sublattices is occupied preferentially. Here, we study a mixed lattice gas with excluded volume interactions only in the grand-canonical formalism with two kinds of particles: small ones, which occupy a single lattice site and large ones, which, when placed on a site, do not allow other particles to occupy its first neighbors also. We solve the model on a Bethe lattice of arbitrary coordination number q. In the parameter space defined by the activities of both particles, at low values of the activity of small particles (z(1)) we find a continuous transition from the fluid to the solid phase as the activity of large particles (z(2)) is increased. At higher values of z(1) the transition becomes discontinuous, both regimes are separated by a tricritical point. The critical line has a negative slope at z(1) = 0 and displays a minimum before reaching the tricritical point, so that a re-entrant behavior is observed for constant values of z(2) in the region of low density of small particles. The isobaric curves of the total density of particles as a function of the density or the activity of small particles show a minimum in the fluid phase.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Phase separation in binary hard-core mixtures: An exact result.

We show that certain lattice models for a binary mixture of hard particle mixtures can be mapped onto a one-component lattice gas or, equivalently, onto an Ising model. The repulsive interaction between unlike particles in the mixture leads to an attractive nearest-neighbour interaction in the one-component lattice gas. In particular, we have found a lattice model of a binary hard-core mixture ...

متن کامل

An approximate analytical solution of the Bethe equation for charged particles in the range of radiotherapy energy

Charged particles such as protons and carbon ions are an increasing tool in radiation therapy. However, unresolved physical problems prevent optimal performance, including estimating the deposited dose in non-homogeneous tissue, is an essential aspect of optimizing treatment. The Monte Carlo (MC) method can be used to estimate the amount of radiation, but, this powerful computing operation is v...

متن کامل

Bethe ansatz solution of triangular trimers on the triangular lattice.

Recently, a model consisting of triangular trimers covering the triangular lattice was introduced and its exact free energy given. In this paper we present the complete calculation leading to this exact result. The solution involves a coordinate Bethe ansatz with two kinds of particles. It is similar to that of the square-triangle random tiling model by Widom and Kalugin. The connection of the ...

متن کامل

Dimer statistics on a Bethe lattice.

We discuss the exact solutions of various models of the statistics of dimer coverings of a Bethe lattice. We reproduce the well-known exact result for noninteracting hard-core dimers by both a very simple geometrical argument and a general algebraic formulation for lattice statistical problems. The algebraic formulation enables us to discuss loop corrections for finite dimensional lattices. For...

متن کامل

Conversion and Residence Time Calculation for Gas-solid Solid Reactions of the Cylindrical-shaped Particles with Con-stant Size Using the Shrinking Core Model

In this paper, a mathematical model is developed to calculate the conversion and the residence time reaction for plug flow and mixed flow in the reactors filled with cylin-drical particles using the shrinking core model. In this modeling, the size of the particles is un-chamged during the reaction. Also, the reaction rate is controlled by the gas layer resistance, the ash layer resistance, and ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • The Journal of chemical physics

دوره 135 18  شماره 

صفحات  -

تاریخ انتشار 2011